I have PES, and the numbers for editing are different to WE I think, but you could still do it following these instructions.
Same face as Di Vaio - Juventus
Same hair as Nesta - AC Milan, Italy
Boots - the numbers are different so I don't know what they are on WE. Use the plain boots - base blue, line 1 white, line 2 blue, tongue red, studs red/white not sure.
hope this helps
