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i can't say exactly. I also had ANT Patch on PC many years back, i think i played in PES 2012 or something. I think that was the last one, maybe PES 2013 also. Can't remember who made this patch.
If you want to have all national teams on newer PES versions, you can use the PS4 exports we made here in this forum for PES 2017 and convert them first to PES 2018 PS4 and then to PES 2018 PC. But that needs much of effort and time to do.
Tutorial converting PES 2017 PS4 teams to PES 2018 PS4 teams (by ggdaris):
Tutorial converting PES 2018 PS4 teams to PES 2018 PC teams (by pes-patch.com):
You can search https://www.evo-web.co.uk/ for more possibilities maybe you find something.