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At main menu, press the following:
L2, R2, R2, L2, Up, Down, Left, Down, Left, X to unlock saving all penalties.
I made a bet with my friend (10 NIS, about 3$) that there are no cheats/hacks what so ever in PES 2010.
I mean cheats like scoring all freekicks, saving all penalties, running faster etc.
So, are they any?
Unless you use software or a cheats disc then no. There aren't any "Press this button combination" etc type cheats.
Enjoy the $3.