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If you want to import another users team, they would need to upload it to a file sharing site (megaupload, rapidshare) they will zip the file so you will need something like winrar to download it to the pc. Then to take it from the pc to the PS3 you would make a folder PS3 in that make another called SAVEDATA and extract the files to that folder. Put the USB in the ps3 go to game utility and find the USB icon press triangle if nothing comes up and your team files should be there. Get pes on go to edit > import and follow the instructions...make sure the teams you are importing have the same region code as your game
you can cherry pick by 1) if someone exports a club for your, or 2) you set up that extra account and export them from someone's OF then copy them to your regular account and import to your in-use option file. Works just like stadiums. Check out the share team and import/export threads for any available.
It does come with some problems with rosters because you are overwriting your current OF roster (even the PES fake teams) with an import. For some players you have to choose what player you want to overwrite. I think the best option is to overwrite a blank "unregistered" slot so you don't overwrite a real player mistakenly.