divide any colour by 4 and you should get the PES 2014 colour
255/4 = 63
so taking the Photoshop colour and dividing it by 4 will get you the ingame colour, if the value is a decimal and higher than 0.5, round it up to the nearest number e.g.
10.5 will be 11
10.75 will be 11
10.45 will be...