Umm... Sorry to bother you people with my silly Q's... -_-
I am all updated now. The burning process worked all good, no problems at all. I just extraced the .rar into a suitable location, started Nero, chose "New", chose "CD", then "CD-ROM (ISO)", marked "No Multisession", then I clicked "Open...", found the .cue file (which is in the same folder as the .bin, obviously), let it load into the CD and finally I could start burning it by clicking on "Burns the current compilation" button. Once the burning was done, I simply followed the guide which Zygalski refers to in the first post in this topic. Easy as that it was. Note: For those who still haven't seen what Zygalski wrote, the .bin and .cue version is for people who have chipped/modded PS2's! Note: Do not burn the .bin file onto your disc, JUST the .cue file!
Since I found many incorrect, but yet so small details, I thought it'd be nice to change them. I've now changed about 90% of the "missing" names and their appearance (this goes for the players in Bundesliga, Le Championat, English Premiership, Boca Juniors, Celtic, Rangers, FC Porto and the other teams on that page and some national teams as well). So, now they look a bit more real than they did before the editing. Note: By appearance I mean the way the look... eyes, face, hair, height, weight, dominant foot etc. Oh... yeah, it took me about 3-4hrs to go through 'em all, and I am still not done.
Again, credits to those who bothered to do all the kits, names, stadiums and logos. It's a real nice piece of work they've done there.
About the .bin & .cue files: There really shouldn't be any problems to burn them. However, I'd suggest you people to use the OLD Nero and NOT the ones with the "StartSmart" (which is btw totally useless and pathetic), as they usually work way better than the new Nero... for some unknown reasons. So far I've had zero problems with my Nero copy and its burning qualities.
Oh well, back to Master League, 4 star difficulty. Trying to develope my players the way the should by regular trainings and various traning methods.