http://d.turboupload.com/d/364640/WorldSocce_OPTIONFILE1.zip.html
Above is a link to an slightly tweaked versions of Watson's awesome Option file. It's in WE9 Xbox format so you will need to convert it with the PESFan Editor if you want to use it on PES 5. The important changes are:
-I have gone thru every team in the game (apart from the Classic teams for obvious reasons) and set appropriate kick takers for Short and Long Free Kicks, Left and Right Corners, and Penalties. You may disagree with some of my choices as there are often multiple players on a team with similar kicking skills, but now every set piece kick will be taken by someone suited to taking it.
-I have altered the starting line-ups and strategies for about 15% of the teams. (I like to SQUARE be left attack, CIRCLE to be right attack and TRIANGLE to be counter attack.) These were the teams I expect to play as at some point and I wanted their line-ups to suit me. For example, I replaced Ze Roberto with Juninho on Brazil because I simply prefer him. There are no wacky changes. Usually I just replaced average players with better players - Ajax is a good example of this.
Minor changes:
1. Changed some of the team names back to what they were in PESFan PES 5 V2 Option file. This is just personal preference.
2. Changed some of the League names so they suit my Master League.
3. Corrected/changed a few Stadium names to Olympiastadion Munchen, Niigata Big Swan, Signal-Iduna-Park, Mestala and Saitama Stadium.
4. Edited Ronaldinho so his Reponse is 80 and his FK accuracy is 87. Edited Carew of Lyon to remove his star for "Side" and add a star for "Scoring".
5. Robben put back on the Netherlands.